LHV vs HHV Efficiency (LHV / HHV)

LHV vs HHV hydrogen efficiency is a choice of energy basis: 33.3 kWh/kg (lower heating value) or 39.4 kWh/kg (higher heating value), which changes one electrolyzer's quoted efficiency.

ElectrolysisLast reviewed by Soukayna Jermouni

In plain terms

Burning a kilogram of hydrogen releases energy, and part of that leaves as water vapour. The lower heating value (LHV) assumes the vapour stays a gas. The higher heating value (HHV) assumes it condenses and returns its latent heat. For hydrogen, NREL gives 33.31 kWh/kg (LHV) and 39.42 kWh/kg (HHV).

Electrolyzer efficiency is that heating value divided by the specific energy consumption:

Efficiency (LHV) = 33.3 / SEC
Efficiency (HHV) = 39.4 / SEC

So one machine has two honest efficiencies, about 18 % apart.

Typical range

Take a system at 55 kWh/kg, the US DOE 2022 status for both alkaline and PEM:

BasisCalculationEfficiency
LHV33.3 / 5561 % (as printed by DOE)
HHV39.4 / 5572 %

The US DOE states its targets on an LHV basis. The Clean Hydrogen JU gives kWh/kg, with an LHV basis implied.

Why it moves LCOH

It doesn't, and that is the point. LCOH depends on kWh/kg, which is the same on either basis. Efficiency percentages only matter when someone converts them back into kWh/kg. If the basis is wrong, the electricity cost in the model is wrong by up to 18 %.

Common mistake

Typical range

33.3 / 39.4 kWh/kg H₂ (LHV / HHV)[1]

Sources

  1. Current (2009) State-of-the-Art Hydrogen Production Cost Estimate Using Water Electrolysis (NREL/BK-6A1-46676), section 4.1.4, National Renewable Energy Laboratory, for the US DOE Hydrogen Program, 2009
  2. Technical Targets for Proton Exchange Membrane Electrolysis, U.S. Department of Energy, Hydrogen and Fuel Cell Technologies Office, 2022

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